In Romance of The Three Kingdoms XIV, players have the opportunity to battle through seven challenging scenarios, including the chaotic war that heralded the beginning of time (the Yellow Turban Rebellion), the struggle for supremacy between Yuan Shao and Cao Cao (the Battle of Guandu), and the start of Zhuge Liang's Northern Campaign (Chu Shi Biao). Each scenario not only offers a wealth of colorful and wild forces but also features many scenes that depict the famous events of that era. These scenes are triggered once players meet certain conditions and showcase events such as the first meeting between Liu Bei and Zhuge Liang.

Additionally, RTK14 includes over 1,000 highly unique officers throughout the game. There are more than 150 character traits, some of which are useful in battle, some in administration, and some are specific to certain officers in the game. For example, Zhang Fei is one of the strongest warriors in history and possesses a unique trait that prevents him from panicking on the battlefield. At the same time, the general is burdened by a character trait that makes it impossible for him to ignore an enemy on the battlefield. Together, these are used to highlight the various aspects of Zhang Fei's personality.