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Regularity and Approximability of Electronic Wave Functions

English, Harry Yserentant, 2010
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The electronic Schrödinger equation describes the motion of N electrons under Coulomb interaction forces in a field of clamped nuclei. Solutions of this equation depend on 3N variables, three spatial dimensions for each electron. Approximating the solutions is thus inordinately challenging, and it is conventionally believed that a reduction to simplified models, such as those of the Hartree-Fock method or density functional theory, is the only tenable approach. This book seeks to convince the reader that this conventional wisdom need not be ironclad: the regularity of the solutions, which increases with the number of electrons, the decay behavior of their mixed derivatives, and the antisymmetry enforced by the Pauli principle contribute properties that allow these functions to be approximated with an order of complexity that comes arbitrarily close to that for a system of one or two electrons. The present notes arose from lectures that I gave in Berlin during the academic year 2008/09 to introduce beginning graduate students of mathematics to this subject. They are kept at an intermediate level that should be accessible to an audience of this kind as well as to physicists and theoretical chemists with corresponding mathematical training.

Key specifications

Language
English
Author
Harry Yserentant
Year
2010
Number of pages
188
Book cover
Paperback

General information

Item number
15921713
Publisher
Springer
Category
Reference books
Release date
29.5.2021

Book properties

Language
English
Author
Harry Yserentant
Year
2010
Number of pages
188
Book cover
Paperback

Voluntary climate contribution

CO₂ emissions
0,5 kg
Climate contribution
EUR 0,12

Product dimensions

Weight
188 g

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