Yes, you can dispense hot water with the De'Longhi Nespresso Citiz EN 167 machine, although this is not directly designed as a hot water dispensing function. Here are the steps to get hot water:

- Place a cup under the coffee spout.
- Remove the capsule if one is inserted.
- Press and hold the espresso or lungo button until the desired amount of water has been dispensed.

This process can also be used to rinse the machine or to preheat the coffee cups.